Correction to Equilibrium Overcompensation in Polyelectrolyte Complexes
نویسندگان
چکیده
منابع مشابه
Stepwise disproportionation in polyelectrolyte complexes
Structural properties and the topology of polyelectrolyte complexes (PECs) formed in solution have been investigated under different conditions by Monte Carlo simulations using a coarse-grained model. The extension of individual polyions has been characterized by their radius of gyration, whereas the composition of the complexes has been investigated by their net charge and their internal topol...
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Polyelectrolyte complexes (PEC) are formed by mixing the solutions of oppositely charged polyelectrolytes, which were hitherto deemed "impossible" to process, since they are infusible and brittle when dry. Here, we describe the process of fabricating free-standing micro-patterned PEC films containing array of hollow or filled microchambers by one-step casting with small applied pressure and a P...
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This work examines polyelectrolyte adsorption (exclusively driven by electrostatic attractions) for a model system (DMAEMA, polydimethylaminoethyl methacrylate, adsorbing onto silica) where the adsorbing polycation is more densely charged than the substrate. Variations in the relative charge densities of the polymer and substrate are accomplished by pH, and the polycation is of sufficiently low...
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ژورنال
عنوان ژورنال: Macromolecules
سال: 2017
ISSN: 0024-9297,1520-5835
DOI: 10.1021/acs.macromol.7b01322